Dr. Philippe Perrotin

Postdoctoral Researcher, Chemistry
University of California, Santa Barbara


Ph.D. Inorganic Chemistry, 2007
University of Idaho

M.Sc. Organic Chemistry, 2001
Université Pierre et Marie Curie (Paris 6)

Postdoctoral Research Associate, 2007-2008
Université de Montre

 

 

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Research Project

 

 

Awards

University of Idaho Presidential Doctoral Fellowship, 2006-2007

 

Publications

Perrotin, P.; El-Zoghbi, I.; Oguadinma, P. O; Schaper, F. Replacing chloride by alkoxide: Cp2Zr(H)OR, searching for alternatives to Schwartz’ reagent.  Organometallics 2009, 28, 4912.

Perrotin, P.; Shapiro, P. J.; Williams, M.; Twamley, B. In Search of a Versatile Pathway to ansa-Chromocene Complexes. Synthesis and Characterization of the Highly Unstable ansa-Chromocene Carbonyl Complex Me2C(C5H4)2CrCO. Organometallics 2007, 26, 1823.

Shapiro, P. J.; Sinnema, P.J.; Perrotin, P.; Budzelaar, P. H. M.; Weihe, H.;Twamley Twamley, B.; Zehnder, R.; Nairn J. Borylated ansa-Chromocene Complexes with CrIII and CrIV Centers. Reaction of the Zwitterionic complex [C5H4(CMe2)2C5H3(C6F5)3]Cr with substrates. Chem. Eur. J. 2007, 13, 6212.

Perrotin, P; Twamley, B.; Shapiro, P. J. Si-bridged Magnesocene, Me2Si(η5-C5H4)2Mg(THF)2. Acta Cryst. 2007, E63, m1277.

Cantrell, T.; Perrotin, P.; Twamley, B.; Shapiro, P. J. Tris-(1-inden-1-yl)-phosphane. Acta Cryst. 2007, E63, o2044.

Foo, D. M.; Zehnder, R.; Perrotin, P.; Leitch, S.; Shapiro, P. J.; Twamley, B.; Budzelaar, P. M. H. ansa-Chromocene complexes. 2. Isocyanide derivates of Cr(II) and Cr(III), their syntheses, X-ray crystal structures, and physical properties. Organometallics, 2006, 25, 719.

Perrotin, P.; Sinnema, P.-J.; Shapiro, P. J. A new, convenient method for labeling cyclopentadienyl ligands with deuterium. Organometallics 2006, 25, 2104.

Shapiro, P. J.; Lee, S.J.; Perrotin, P.; Cantrell, T.; Blumenfeld, A.; Twamley, B. The first example of an ansa-bis(cyclopentadienyl)aluminum compound. X-ray crystallographic characterization of [Me4C2(C5H4)2Al-µ-Cl]2 and its monomeric THF and t-BuNC adducts. NMR spectroscopic characterization of the structures and fluxional behavior of these compounds in solution” Polyhedron 2005, 24,1366.

 

Presentations

Perrotin, P.; Shapiro, P. J.; Twamley, B. “Preparation and X-ray Characterization of Cyclopentadienyl Gallium Azo Compounds.” Northwest Regional Meeting of the American Chemical Society, Boise, ID, United States, June 2007

Perrotin, P.; Shapiro, P. J.; Twamley, B. “Cyclopentadienylgallium Azo Derivatives: Potential GaN Precursors?” American Chemical Society National Meeting, San Francisco, CA, United States, Sept. 2006.

Perrotin, P.; Shapiro, P. J.; Twamley, B. “Cyclopentadienyl Gallium Compounds as Potential Precursors to Gallium Nitride Materials.” American Chemical Society National Meeting, Washington D.C., United States, August 2005.

Perrotin, P.; Shapiro, P. J.; Twamley, B. “New Synthetic Approach to Ansa-Calcocenes Compounds.” American Chemical Society National Meeting, Washington D.C., United States, August 2005.

Perrotin, P.; Shapiro, P. J. “Deuterium Labeling of Bridged and Unbridged Calcocenes” International Conference of Coordination Chemistry 36th, Merida, Mexico, July 2004.